Article Details
Synthesis Methods for Halogenated Calix[4]Arenes
Author(s):
Ekaterina A. Ivanova, Polina E. Prokhorova and
Yury Y. MorzherinPages 245-254 (10)
Abstract:
This review presents synthesis methods for halogenated calix[4]arenes at the
upper rim and in meta-position of phenolic unit as well as at the lower rim by
substitution of hydroxyl group by halogen atom; methods for introducing the
atom of iodine, bromine and chlorine into the molecule of calix[4]arenes; the
advantages and disadvantages of each method.
Keywords:
Bromination, Calix[4]arenes, chlorination,
fluorination, halogenation, iodination, ipso-iodination.
Affiliation:
Department of Technology for Organic Synthesis,
Chemical Technology Institute, Ural Federal University, 19 Mira St.,
Yekaterinburg, Russia 620002.
Graphical Abstract:
This review presents synthesis methods for halogenated calix[4]arenes at the upper rim and in meta-position of phenolic unit as well as at the lower rim by substitution of hydroxyl group by halogen atom; methods for introducing the atom of iodine, bromine and chlorine into the molecule of calix[4]arenes; the advantages and disadvantages of each method.
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